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With Tiger Woods absent injured, the tournament is expected to be one of the most open for years andNorthern Ireland's McDowell would not be surprised to see some of the game's lesser lights stealing the limelight.
"Some of the rookies today have a great chance," McDowell said in his BBC column.
"I played with Harris English a few weeks ago at Bay Hill. There's a kid making his Augusta debut and if he was on the leader board come the weekend I would not be shocked.
"He's long, hits his irons very high, very cool, and has a good short game and putter.
"You know he's got the tools to win around Augusta. These young players are just so well equipped nowadays.
"They are better athletes and they're fearless. They're growing up in an era where they've watched Tiger Woods do things with a golf ball that seemed impossible."
First-timer Zoeller famously won the 1979 Masters but it has not happened since at a tournament which usually ends with a big-name champion.
"The belief level globally now for a young professional is so much better than it used to be," McDowell said.
"The Zoeller-type first-time, rookie champion could happen in any of the majors now - this one included.
"It could be an amazing week for the game, with one of the new breed making a name for himself and coming out of the shadow of Tiger.
"He has taken the game to new heights but with him absent there's a real chance for someone else to take the headlines."